Controlled/Living Radical Polymerization: Progress in RAFT, by Krzysztof Matyjaszewski (Eds.)

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Extra info for Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP

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Lange, R. F. ; Klumperman, B. Macromolecules 2006, 39, 7796-7797. Chong, Y. ; Le, T. P. ; Thang, S. H. Macromolecules 1999, 32, 2071-2074. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2009. ch004 Chapter 4 Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity Harumi Murayama, Kotaro Satoh, and Masami Kamigaito Department of Applied Chemistry, Graduate School o f Engineering, Nagoya University, Nagoya 464-8603, Japan Thiourea derivatives were examined for the stereospecific radical polymerization of acrylamides via hydrogen-bonding interactions between the additives and the monomers and/or the growing polymer terminals.

The anthracene derivative (8) also inhibited the radical polymerization. All these effects for NIPMA showed similar tendencies to those for DMAM although the changes were slightly lower. The effects of the amounts of 1–3 were also investigated for NIPAM in CH2Cl2 at –78 °C (Figure 2). Upon increasing the amounts, the m value gradually increased and reached an almost constant value. 5 equivalent to NIPAM was not effective for increasing the tacticity. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2009.

1993, 49, 2179-2188. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2009. ch003 Chapter 3 RAFT Polymerization of Vinyl Acetate, Styrene and Acrylates Using N,N-Dithiocarbamates Vidyasagar Malepu, Christy D. Petruczok, TuTrinh Tran, Tianxi Zhang, Mahesh Thopasridharan and Devon A. Shipp* Department of Chemistry and Biomolecular Science, and Center for Advanced Materials Processing Clarkson University, Potsdam, NY 13699-5810, USA Homo- and block-copolymers comprised of vinyl acetate, styrene, methyl acrylate and tert-butyl acrylate monomers were prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization using N,N-dithiocarbamates as transfer agents.

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