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By Yoshiki Chujo
Edited and authored via most sensible foreign specialists, this primary booklet on conjugated polymers with a spotlight on synthesis offers a close evaluation of all smooth artificial tools for those hugely fascinating compounds. As such, it describes each vital compound classification, together with polysilanes, organoboron compounds, and ferrocene-containing conjugated polymers. An necessary resource for each artificial polymer chemist.Content:
Chapter 1 Organometallic Polycondensation for Conjugated Polymers (pages 1–33): Takakazu Yamamoto
Chapter 2 Catalyst?Transfer Condensation Polymerization for Precision Synthesis of ??Conjugated Polymers (pages 35–58): Tsutomu Yokozawa
Chapter three Regioregular and Regiosymmetric Polythiophenes (pages 59–90): Itaru Osaka and Richard D. McCullough
Chapter four sensible Hyperbranched Polymers made out of Acetylenic An?Type development Blocks (pages 91–131): Jianzhao Liu, Jacky W. Y. Lam and Ben Zhong Tang
Chapter five Through?Space Conjugated Polymers (pages 133–163): Yasuhiro Morisaki and Prof. Yoshiki Chujo
Chapter 6 absolutely Conjugated Nano?Sized Macrocycles: Syntheses and flexible houses (pages 165–194): Masayoshi Takase and Masahiko Iyoda
Chapter 7 Organoboron Conjugated Polymers (pages 195–213): Atsushi Nagai and Prof. Yoshiki Chujo
Chapter eight contemporary advancements in ??Conjugated Macromolecules with Phosphorus Atoms generally Chain (pages 215–227): Paul W. Siu and Derek P. Gates
Chapter nine Organo?Arsenic, Phosphorus, and Antimony Conjugated Polymers (pages 229–249): Kensuke Naka and Prof. Yoshiki Chujo
Chapter 10 artificial recommendations to Conjugated Main?Chain Metallopolymers (pages 251–287): Andreas Wild, Andreas iciness, Martin D. Hager and Ulrich S. Schubert
Chapter eleven Helical Polyacetylene ready in a Liquid Crystal box (pages 289–301): Kazuo Akagi
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Extra resources for Conjugated Polymer Synthesis: Methods and Reactions
Sample text
1994) Electrochim. J. (1989) Synth. , and Yoshimura, S. (1994) Synth. , 66, 157. , and Mori, C. (1990) Chem. , and Mori, C. (1990) Synth. , and Yamamoto, T. , 83, 771. , and Zamboni, R. (1993) Synth. , and Br€ ukner, S. (1993) Synth. , and Br€ ukner, S. , and Garnier, F. (1993) Adv. , 5, 461; (e) Taliani, C. M. (1996) Adv. E. (1996) Chem. , 8, 2836. 38 (a) Yamamoto, T. (1996) Chem. , and Sasaki, S. (1997) Chem. , and Kubota, K. (1997) Chem. , 9, 1217; (d) Gonzalez Londa, L. C. , and Holdcroft, S.
9) [4c,e, f,19g,29a]. PBpy forms metal complexes [4e,f ], and various p-conjugated chelating polymers and their metal complexes have been synthesized and their electric and optical properties investigated [4c,12i,21,28,39a–g]. Other types of transition metal complexes have also been synthesized using PPP and its analogues [39h–k]. Ferrocene polymers have also been reported [20c,35,39k–m]. In the case of N-containing poly(arylene)s, chemical modification of imine nitrogen is also possible. For instance, quaternization with RX [40], N-oxidation with H2O2 [41], and N-ylidation with tetracyanoethylene oxide [41b] have been carried out for these polymers.
Soc. , 81, 536. , and Sasaki, S. (1996) J. Phys. , 30, 12631; (b) Yamamoto, T. and Etori, H. , and Osakada, K. (1992) Polym. , 29, 597, the reflection spectrum of PCyh indicates that it has an absorption peak at about 600nm (T. Yamamoto and T. Fukuda, unpublished data). ) [22d]. The degree of the red shift (cf. , and Ikeda, S. (1974) J. Polym. , Polym. Chem. , and Okamoto, S. (1961) J. Polym. W. M. , and Kanbara, T. (1992) J. Phys. , 96, 8677. , and Tokuda, K. (1991) J. Chem. , Chem. , and Yamamoto, T.