Conductive Electroactive Polymers: Intelligent Materials by Gordon G. Wallace

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By Gordon G. Wallace

From the authors' preface:
"As we input the period of clever fabrics and embark upon a brand new method of fabric layout, synthesis, and method integration, definite teams of fabrics will grow to be champions."

Standing excessive between those champions are conductive electroactive polymers (CEPs), which seem destined to play a important function within the improvement of clever fabrics. even though contemporary advances have enabled the layout and meeting of polymers from the molecular point, developing subtle constructions calls for a superb realizing of the structure-property relationships.

Building at the standard-setting first version, Conductive Electroactive Polymers: clever fabrics platforms, moment version presents a radical, updated creation to conductive electroactive polymers. The authors speak about the parameters that have an effect on the formation of significant CEPs, together with polypyrroles, polyanilines, and polythiophenes. They exhibit the best way to use those parameters to govern the houses of the polymers, and so they make clear the chemical and effort parameters that ascertain the constitution and its properties.

New during this variation are extra info on polythiphene and polyaniline platforms, an replace on growth in polypyrroles, and stories on contemporary advances in CEP processing strategies and machine fabrication.

As using clever fabrics grows, it turns into more and more very important for scientists and engineers in fields starting from fabrics technology to electronics and biomedicine to appreciate the houses and capability of CEPs. This e-book is an exceptional advent to engaging in polymers and a useful reference that brings you quick brand new on contemporary advancements.

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Extra resources for Conductive Electroactive Polymers: Intelligent Materials Systems, Second Edition

Example text

It has been speculated59 that the dopant could be designed such that it acts as a corrosion inhibitor for the metal and so the polymer can release the inhibitor at the point when corrosive conditions first form. Indeed, a number of studies have shown that the dopant used with PAn has a large impact on the corrosion protection provided by the polyaniline, suggesting that the inhibition process may be involved in the corrosion protection. Both anionic and cationic species can be incorporated into the polymer and released at the desired time.

It was only the subsequent development of other in situ techniques that revealed the complexities that take us closer to fully understanding and controlling the behavior of CEPs. Electrochemical quartz crystal microbalance (EQCM) A system developed recently sheds further light on these dynamic processes. The technique is the EQCM, wherein the polymer is deposited on a goldcoated quartz crystal. 20(b). , those containing polyelectrolytes wherein cation movement rather than anion predominates and this is reflected in increases in mass at negative potentials.

The sensitivity at present is limited primarily by the method of sensor fabrication; the detection limit is lowered by producing ultrathin and coherent layers of the conducting polymer. Screen printing and ink-jet printing techniques provide some interesting opportunities in this regard. Improvements in device fabrication should expand applications into the environmental and biomedical areas. 17 Resistance change during stretching of PPy-coated Lycra®. (Graph courtesy of T. ) © 2003 by CRC Press LLC Physical sensors Conducting polymers have also been used as sensors for the physical environment, particularly for strain or stress.

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