By Frank Miller
A brand new deluxe exchange paperback version of 1 of the main vital and severely acclaimed Batman adventures ever, written through Frank Miller, writer of THE darkish KNIGHT RETURNS! as well as telling the complete dramatic tale of Batman's first yr struggling with crime, this assortment comprises reproductions of unique pencils, promotional paintings, script pages, unseen David Mazzucchelli Batman paintings and extra.
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Extra info for Batman: Year One
1 Main Structural Principles 15 Macroligands for type I MMC should be classified according to the prehistory of their formation (polymerization, copolymerization, grafting polymerization, polycondensation, polymer analogous reactions) and then by their functionality. Although such a two-parameter classification is schematic, it more or less definitively characterizes the macroligand. The formation oftype II MMC can be described similarly via a polycondensation or polyaddition reaction. Type III materials are obtained via physical incorporation into the carrier.
T,H. 't+OCH,CH, rA, ~ Y tooH CH2 KMn04 ~ H2-o ~ ~/CHO HO COONa ~ $ -¥ h L. -@ rr\ ~, H. Ol: Q N " ~. 3. 4. 5. The principal ways of S- and As-groups introduction into macroiigands on the base ofCMCS benzoic and itaconic acids, maleic anhydride, etc. Macrolignads with donoracceptor groups are produced by poly- and copolymerization of methylmethacrylate (MMA), vinylacetate (VA), acrylamide (AAm), N-vinylpyrrolidone, vinylpyridine (VP), vinylimidazole, acrylonitrile, vinyldiphenylphosphine, etc. Polymeric Schiff bases can also be formed by polymerization of respective monomers, such as 2-butyl-amino-4-vinylphenole or I-hydroxy-5vinylbenzaldehyde .
25)). ) and of polymer chains inside of these structural elements . Therefore, MXn affects not only processes of molecular, but also supramolecular, organization. Another point to consider is the destruction of the polymer chain of the macroligand of type I MMC during MMC formation. This phenomenon is often observed even in diluted solution (including nonaqueous ones) under inert atmosphere. Viscosimetry, GPC, and rapid sedimentation techniques are usually used to reveal this aspect [56, 57].